地坪涂料水性化技術進展
地(di)坪(ping)涂料(liao)具有無接(jie)縫(feng)、整體裝飾性好、表面光潔、易于清潔,以(yi)及物(wu)理機(ji)械性能(neng)(neng)和耐化學品性能(neng)(neng)優(you)良,價格適中,施工(gong)(gong)(gong)簡(jian)便(bian),維修方便(bian)等諸(zhu)多特(te)點。另(ling)外,地(di)坪(ping)涂料(liao)還可根(gen)據特(te)殊需求,賦(fu)予地(di)坪(ping)防(fang)(fang)(fang)靜電、防(fang)(fang)(fang)沖(chong)擊火(huo)花(hua)、耐高(gao)溫、防(fang)(fang)(fang)滑(hua)等特(te)殊功能(neng)(neng),相比于其它地(di)坪(ping)材料(liao),更能(neng)(neng)滿足現代工(gong)(gong)(gong)業生產(chan)對地(di)坪(ping)的不(bu)同要求。正是(shi)基于這些(xie)特(te)點,現代建筑,特(te)別是(shi)現代工(gong)(gong)(gong)業車間,如食(shi)品加(jia)工(gong)(gong)(gong)、制藥、機(ji)械電子、儀器儀表、化工(gong)(gong)(gong)、航(hang)空、汽車等行業,大量使用地(di)坪(ping)涂料(liao)。
1地坪涂料現狀
我國的(de)地坪涂(tu)(tu)(tu)料(liao)產(chan)業始(shi)于(yu)20世紀90年(nian)代初期,隨著我國經濟的(de)快(kuai)速(su)發展(zhan),尤(you)其(qi)是現代醫藥、電子(zi)、食品等行業的(de)高速(su)增長(chang),帶動了地坪涂(tu)(tu)(tu)料(liao)的(de)市場(chang)需求量。地坪涂(tu)(tu)(tu)料(liao)已(yi)成為我國近年(nian)來涂(tu)(tu)(tu)料(liao)行業中繼建(jian)筑涂(tu)(tu)(tu)料(liao)、交通車(che)輛涂(tu)(tu)(tu)料(liao)、家(jia)具木器涂(tu)(tu)(tu)料(liao)以及海洋(yang)防腐涂(tu)(tu)(tu)料(liao)后,發展(zhan)最快(kuai)的(de)涂(tu)(tu)(tu)料(liao)品種之一。
地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)主要有兩(liang)大類:環氧地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)和聚氨酯(zhi)地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)[1]。環氧地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)具(ju)(ju)有硬度(du)高、抗(kang)壓強度(du)高、耐(nai)磨(mo)性(xing)(xing)好、耐(nai)化學品性(xing)(xing)優(you)良等優(you)點,但質脆、易裂,耐(nai)候性(xing)(xing)差,通常(chang)應(ying)用于(yu)紫外(wai)線(xian)較(jiao)弱的(de)室內(nei)場所或作(zuo)底漆使用,由于(yu)使用成本相對(dui)便宜,得到了(le)廣(guang)泛應(ying)用,約(yue)占整(zheng)個地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)市(shi)場的(de)70%。聚氨酯(zhi)地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)盡管在硬度(du)和強度(du)方面稍遜于(yu)環氧地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao),但其(qi)各項(xiang)性(xing)(xing)能具(ju)(ju)有廣(guang)泛的(de)可調節(jie)性(xing)(xing),具(ju)(ju)有更(geng)好的(de)柔(rou)韌性(xing)(xing)、耐(nai)沖擊性(xing)(xing)、耐(nai)磨(mo)性(xing)(xing)、耐(nai)有機酸性(xing)(xing)、良好的(de)抗(kang)紫外(wai)線(xian)性(xing)(xing)及耐(nai)化學腐蝕性(xing)(xing)等,行(xing)人行(xing)走時腳(jiao)感舒適,緩解疲勞,并可隔音減噪,而且(qie)具(ju)(ju)有優(you)異(yi)的(de)戶外(wai)耐(nai)候性(xing)(xing),比環氧地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)的(de)應(ying)用范(fan)圍更(geng)廣(guang)。由于(yu)其(qi)使用成本較(jiao)高,用量約(yue)占整(zheng)個地(di)(di)(di)(di)坪(ping)(ping)(ping)(ping)涂(tu)(tu)料(liao)市(shi)場的(de)25%。
隨著全民健身理念日益深(shen)入(ru)民心,大(da)到(dao)每個城市,小到(dao)每個社(she)區或單位(wei),都將會建造更(geng)多(duo)類別(bie)的(de)(de)體育場(chang)館和(he)場(chang)地(di),為健身和(he)比賽(sai)提供便(bian)利,這些場(chang)地(di)無論是(shi)(shi)耐候性的(de)(de)需要,還(huan)是(shi)(shi)人(ren)體舒適度的(de)(de)需要,聚(ju)氨酯地(di)坪(ping)涂(tu)料都是(shi)(shi)地(di)坪(ping)涂(tu)裝面(mian)層的(de)(de)理想(xiang)選擇,相信聚(ju)氨酯地(di)坪(ping)涂(tu)料的(de)(de)使用比例會不斷提高。
目前我國地(di)坪(ping)(ping)涂(tu)(tu)(tu)料(liao)(liao)80%以上為溶(rong)劑(ji)(ji)(ji)(ji)型涂(tu)(tu)(tu)料(liao)(liao),其余的(de)(de)(de)(de)(de)主要(yao)為無溶(rong)劑(ji)(ji)(ji)(ji)環氧(yang)涂(tu)(tu)(tu)料(liao)(liao)和聚脲噴涂(tu)(tu)(tu)體,水(shui)性(xing)地(di)坪(ping)(ping)涂(tu)(tu)(tu)料(liao)(liao)所占比例很小(xiao)。溶(rong)劑(ji)(ji)(ji)(ji)型地(di)坪(ping)(ping)涂(tu)(tu)(tu)料(liao)(liao)中(zhong)含(han)有(you)(you)(you)較(jiao)多的(de)(de)(de)(de)(de)有(you)(you)(you)機(ji)溶(rong)劑(ji)(ji)(ji)(ji),這些(xie)有(you)(you)(you)機(ji)溶(rong)劑(ji)(ji)(ji)(ji)在(zai)涂(tu)(tu)(tu)料(liao)(liao)的(de)(de)(de)(de)(de)生產和施(shi)工(gong)期間排(pai)入(ru)大(da)氣,污染(ran)環境,同時危害人類健(jian)康;此(ci)外溶(rong)劑(ji)(ji)(ji)(ji)型聚氨酯地(di)坪(ping)(ping)涂(tu)(tu)(tu)料(liao)(liao)中(zhong)還含(han)有(you)(you)(you)游離的(de)(de)(de)(de)(de)異(yi)氰酸酯單體,在(zai)施(shi)工(gong)過程中(zhong),會嚴(yan)重影響(xiang)人體健(jian)康和生活環境。而(er)(er)無溶(rong)劑(ji)(ji)(ji)(ji)環氧(yang)地(di)坪(ping)(ping)涂(tu)(tu)(tu)料(liao)(liao)中(zhong)含(han)有(you)(you)(you)少量的(de)(de)(de)(de)(de)活性(xing)稀(xi)釋劑(ji)(ji)(ji)(ji),常(chang)用的(de)(de)(de)(de)(de)活性(xing)稀(xi)釋劑(ji)(ji)(ji)(ji)為丁基(ji)(ji)環氧(yang)丙(bing)基(ji)(ji)醚(有(you)(you)(you)一(yi)定毒(du)性(xing)),成(cheng)本較(jiao)高且仍含(han)有(you)(you)(you)一(yi)定量的(de)(de)(de)(de)(de)揮(hui)發性(xing)有(you)(you)(you)機(ji)溶(rong)劑(ji)(ji)(ji)(ji)。溶(rong)劑(ji)(ji)(ji)(ji)型地(di)坪(ping)(ping)涂(tu)(tu)(tu)料(liao)(liao)在(zai)實(shi)際施(shi)工(gong)中(zhong)還存(cun)在(zai)許多難以克服的(de)(de)(de)(de)(de)弊病,如起泡、鼓泡、脫落、附(fu)著不良等,會受到環境溫濕度、基(ji)(ji)層濕度,以及基(ji)(ji)面的(de)(de)(de)(de)(de)其它問(wen)題的(de)(de)(de)(de)(de)影響(xiang),特(te)別是(shi)對基(ji)(ji)材的(de)(de)(de)(de)(de)干燥(zao)程度要(yao)求(qiu)很高,而(er)(er)實(shi)際施(shi)工(gong)時很難滿足要(yao)求(qiu)。
水性地(di)坪涂料(liao)對基材的(de)干燥程度要求低(di),施(shi)(shi)工(gong)(gong)工(gong)(gong)具(ju)可用水直接(jie)清(qing)洗,涂料(liao)的(de)配制和施(shi)(shi)工(gong)(gong)操(cao)作安(an)全方(fang)便(bian),而(er)且涂料(liao)不(bu)(bu)燃、不(bu)(bu)爆(bao)、安(an)全,貯存和運輸方(fang)便(bian),避免(mian)了溶劑型涂料(liao)因儲存運輸和使用不(bu)(bu)當而(er)引起(qi)的(de)爆(bao)炸和火災事故。近幾年,隨著國際原油價格的(de)飛速增長和居(ju)高不(bu)(bu)下,有機溶劑等基本化(hua)工(gong)(gong)原料(liao)的(de)價格普遍上揚,我國是一(yi)(yi)個石油資源緊(jin)張的(de)國家,同時(shi)又是一(yi)(yi)個石油消費大國,節省資源已成(cheng)為我國今后(hou)一(yi)(yi)項(xiang)長期而(er)又緊(jin)迫(po)的(de)戰略任務。地(di)坪涂料(liao)的(de)水性化(hua)已成(cheng)為必(bi)然趨勢。
下面(mian)就環氧地坪(ping)涂料和(he)雙組分聚氨(an)酯(zhi)地坪(ping)涂料的水性(xing)化技術進展作一些介紹。
2環氧地坪(ping)涂(tu)料的水性化
目前,環氧(yang)(yang)(yang)地坪涂料(liao)水性化(hua)的(de)技(ji)術(shu)主要有2種:一(yi)是將環氧(yang)(yang)(yang)樹脂水性化(hua),然后與水可分(fen)散的(de)環氧(yang)(yang)(yang)固化(hua)劑配(pei)合(he)使(shi)用;二是低相對分(fen)子質量的(de)液態環氧(yang)(yang)(yang)同具有乳化(hua)作用的(de)環氧(yang)(yang)(yang)固化(hua)劑配(pei)合(he)使(shi)用[2]。
2.1環氧樹脂的(de)水性化技術
環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)的(de)(de)(de)(de)(de)(de)水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)化(hua)(hua)(hua)(hua)技(ji)術(shu)主要分(fen)為成鹽法(fa)和乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)法(fa)兩大(da)類[3]。成鹽法(fa)是(shi)(shi)將環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)改(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)成富(fu)含(han)酸或富(fu)含(han)堿(jian)的(de)(de)(de)(de)(de)(de)樹(shu)脂(zhi)(zhi)(zhi),再用堿(jian)或酸進(jin)行中(zhong)和。成鹽技(ji)術(shu)又可分(fen)為醚化(hua)(hua)(hua)(hua)型(xing)、酯化(hua)(hua)(hua)(hua)型(xing)和接枝(zhi)反應型(xing)3類。其中(zhong)前兩種(zhong)方法(fa)均(jun)是(shi)(shi)通(tong)(tong)過打(da)開環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)環(huan)(huan)(huan)(huan)(huan)引入極性(xing)(xing)(xing)(xing)(xing)(xing)(xing)基團,接枝(zhi)反應型(xing)[4-5]是(shi)(shi)通(tong)(tong)過自(zi)由(you)基引發(fa)丙烯酸接枝(zhi)共聚(ju),將親水(shui)(shui)基團引入環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)。成鹽技(ji)術(shu)制(zhi)備(bei)(bei)的(de)(de)(de)(de)(de)(de)水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)分(fen)散相(xiang)(xiang)粒(li)徑達到(dao)納米級,貯(zhu)存穩定(ding)(ding)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)良好,但(dan)體(ti)系(xi)對(dui)pH的(de)(de)(de)(de)(de)(de)變化(hua)(hua)(hua)(hua)適應性(xing)(xing)(xing)(xing)(xing)(xing)(xing)較差(cha),涂膜(mo)的(de)(de)(de)(de)(de)(de)柔韌性(xing)(xing)(xing)(xing)(xing)(xing)(xing)及耐(nai)水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)也不理想。乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)法(fa)制(zhi)備(bei)(bei)水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)的(de)(de)(de)(de)(de)(de)技(ji)術(shu)有(you)(you)2種(zhong):一是(shi)(shi)外加(jia)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)劑(ji)法(fa),通(tong)(tong)過強制(zhi)或相(xiang)(xiang)轉(zhuan)化(hua)(hua)(hua)(hua)法(fa)制(zhi)成環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)乳(ru)(ru)(ru)液(ye)[6],外加(jia)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)劑(ji)強制(zhi)制(zhi)備(bei)(bei)的(de)(de)(de)(de)(de)(de)乳(ru)(ru)(ru)液(ye)分(fen)散相(xiang)(xiang)的(de)(de)(de)(de)(de)(de)微粒(li)尺寸(cun)較大(da),約50μm,乳(ru)(ru)(ru)液(ye)的(de)(de)(de)(de)(de)(de)貯(zhu)存穩定(ding)(ding)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)極差(cha),并(bing)(bing)且(qie)(qie)乳(ru)(ru)(ru)液(ye)的(de)(de)(de)(de)(de)(de)成膜(mo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)能也不好。轉(zhuan)相(xiang)(xiang)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)法(fa)[7-8]是(shi)(shi)通(tong)(tong)過將乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)劑(ji)和環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)混合均(jun)勻,隨后在一定(ding)(ding)的(de)(de)(de)(de)(de)(de)剪切條件下緩慢(man)地(di)向體(ti)系(xi)中(zhong)加(jia)入蒸餾(liu)水(shui)(shui),隨著加(jia)水(shui)(shui)量(liang)的(de)(de)(de)(de)(de)(de)增加(jia),整個體(ti)系(xi)逐步由(you)油包水(shui)(shui)型(xing)向水(shui)(shui)包油型(xing)轉(zhuan)變,形成水(shui)(shui)可稀釋體(ti)系(xi)。但(dan)該(gai)體(ti)系(xi)的(de)(de)(de)(de)(de)(de)貯(zhu)存穩定(ding)(ding)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)及機械穩定(ding)(ding)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)均(jun)比(bi)成鹽法(fa)制(zhi)備(bei)(bei)的(de)(de)(de)(de)(de)(de)水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)差(cha)。目前研(yan)究較為活躍的(de)(de)(de)(de)(de)(de)是(shi)(shi)第(di)2種(zhong)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)技(ji)術(shu),即(ji)環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)自(zi)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)[9-10],在環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)分(fen)子鏈(lian)中(zhong)引入親水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)乙烯鏈(lian)段,同時保(bao)證每(mei)個改(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)后的(de)(de)(de)(de)(de)(de)環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)樹(shu)脂(zhi)(zhi)(zhi)分(fen)子上含(han)有(you)(you)2個環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)基,不用外加(jia)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)劑(ji)即(ji)可自(zi)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)分(fen)散形成乳(ru)(ru)(ru)液(ye),其乳(ru)(ru)(ru)液(ye)的(de)(de)(de)(de)(de)(de)分(fen)散相(xiang)(xiang)粒(li)徑較小,貯(zhu)存穩定(ding)(ding)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)高,體(ti)系(xi)對(dui)pH不敏(min)感(gan),并(bing)(bing)且(qie)(qie)乳(ru)(ru)(ru)化(hua)(hua)(hua)(hua)劑(ji)在成膜(mo)時參與了固化(hua)(hua)(hua)(hua)反應,因此涂膜(mo)的(de)(de)(de)(de)(de)(de)硬(ying)度(du)、附著力也有(you)(you)很大(da)提(ti)高,目前市(shi)售的(de)(de)(de)(de)(de)(de)水(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)環(huan)(huan)(huan)(huan)(huan)氧(yang)(yang)(yang)乳(ru)(ru)(ru)液(ye)多(duo)為此類。
2.2水性環氧地坪涂料固化劑的水性化
水(shui)(shui)性(xing)環(huan)(huan)氧(yang)固化(hua)劑是決定水(shui)(shui)性(xing)環(huan)(huan)氧(yang)地坪(ping)涂(tu)料(liao)最終性(xing)能(neng)(neng)的(de)關鍵因素之一。它(ta)應(ying)能(neng)(neng)較好地溶解或分散在(zai)水(shui)(shui)中(zhong),而(er)且在(zai)水(shui)(shui)中(zhong)能(neng)(neng)夠(gou)穩定存在(zai),與(yu)環(huan)(huan)氧(yang)樹(shu)脂具有良(liang)好的(de)相容性(xing)。該(gai)固化(hua)劑可直接(jie)乳化(hua)環(huan)(huan)氧(yang)樹(shu)脂或與(yu)水(shui)(shui)性(xing)環(huan)(huan)氧(yang)乳液(ye)配成穩定的(de)水(shui)(shui)性(xing)環(huan)(huan)氧(yang)體系(xi),同時(shi)體系(xi)的(de)流變性(xing)、適用(yong)期、固化(hua)條(tiao)件和涂(tu)膜性(xing)能(neng)(neng)也應(ying)滿(man)足(zu)水(shui)(shui)性(xing)環(huan)(huan)氧(yang)地坪(ping)涂(tu)料(liao)的(de)使(shi)用(yong)要求。
到目前(qian)為止(zhi),水性(xing)環(huan)氧地(di)坪(ping)涂(tu)料(liao)用固(gu)(gu)化(hua)(hua)劑(ji)經歷了(le)3代(dai)的(de)發展[11]。第(di)1代(dai)水性(xing)環(huan)氧地(di)坪(ping)涂(tu)料(liao)用固(gu)(gu)化(hua)(hua)劑(ji)采用溶(rong)劑(ji)型環(huan)氧固(gu)(gu)化(hua)(hua)劑(ji)聚酰胺與醋(cu)酸(suan)、磷(lin)酸(suan)或(huo)鹽酸(suan)反應制得銨(an)鹽,再在醇醚類溶(rong)劑(ji)的(de)輔助下溶(rong)于(yu)水而制得。該方法僅改(gai)善了(le)固(gu)(gu)化(hua)(hua)劑(ji)在水中(zhong)的(de)穩定性(xing)和(he)親水性(xing),其涂(tu)膜性(xing)能和(he)固(gu)(gu)化(hua)(hua)性(xing)能仍未得到改(gai)進,存在著(zhu)水稀釋降黏速度緩慢(man)(man)、固(gu)(gu)化(hua)(hua)速率慢(man)(man)、光(guang)澤低、硬度低等(deng)缺點。
在(zai)20世紀80年代(dai)(dai)后期和90年代(dai)(dai)初,開發了(le)以(yi)環脂胺環氧(yang)加成(cheng)物(wu)為(wei)基礎的(de)第2代(dai)(dai)水(shui)性(xing)環氧(yang)固化劑(ji)(ji)(ji)。采用(yong)環氧(yang)樹脂作(zuo)為(wei)擴鏈(lian)劑(ji)(ji)(ji)可以(yi)提高固化劑(ji)(ji)(ji)與環氧(yang)樹脂的(de)相容性(xing),這種(zhong)涂(tu)(tu)料(liao)體系即使在(zai)低(di)溫和高濕環境下也能較快地(di)固化。這種(zhong)水(shui)性(xing)環氧(yang)地(di)坪涂(tu)(tu)料(liao)的(de)缺(que)點是不能厚(hou)(hou)涂(tu)(tu),當一次涂(tu)(tu)膜厚(hou)(hou)度(du)超過500μm時,涂(tu)(tu)膜在(zai)干(gan)燥過程中容易開裂(lie)。
最新(xin)開發的第(di)3代(dai)水性(xing)環(huan)氧(yang)地坪(ping)(ping)涂料固(gu)(gu)(gu)化(hua)劑是以特高(gao)相(xiang)對分(fen)子(zi)質量的脂肪胺(an)環(huan)氧(yang)加(jia)成物(wu)為基礎分(fen)散(san)在(zai)水中的乳(ru)液,具有(you)(you)高(gao)胺(an)官(guan)能度(du)、相(xiang)容性(xing)好(hao)等(deng)特點。混合后(hou)乳(ru)液穩定(ding),固(gu)(gu)(gu)化(hua)速(su)度(du)快,水稀(xi)釋對降低體(ti)系黏度(du)優(you)于第(di)1、2代(dai)體(ti)系,具有(you)(you)較高(gao)的施工(gong)固(gu)(gu)(gu)體(ti)分(fen)。當(dang)涂膜(mo)厚(hou)(hou)度(du)大于1 mm時,仍能很好(hao)干燥(zao),不會出現開裂現象。一次(ci)可涂覆(fu)數毫米(mi)厚(hou)(hou)的地坪(ping)(ping)涂膜(mo),克服(fu)了普通(tong)室溫固(gu)(gu)(gu)化(hua)水性(xing)環(huan)氧(yang)地坪(ping)(ping)涂料不能一次(ci)性(xing)厚(hou)(hou)涂的缺陷,具有(you)(you)良好(hao)的市場(chang)應用(yong)前景。
3雙(shuang)組(zu)分(fen)(fen)聚(ju)(ju)(ju)氨酯(zhi)地坪(ping)涂(tu)(tu)料(liao)(liao)的(de)(de)水(shui)(shui)性(xing)(xing)(xing)化聚(ju)(ju)(ju)氨酯(zhi)最早的(de)(de)水(shui)(shui)性(xing)(xing)(xing)化產(chan)物是(shi)(shi)(shi)單組(zu)分(fen)(fen)水(shui)(shui)性(xing)(xing)(xing)聚(ju)(ju)(ju)氨酯(zhi),其(qi)具(ju)有(you)較(jiao)高(gao)的(de)(de)斷裂伸長率和(he)(he)(he)(he)適當(dang)(dang)的(de)(de)強度(du),并能常溫(wen)物理干燥,但是(shi)(shi)(shi)由(you)于較(jiao)低(di)的(de)(de)相(xiang)對分(fen)(fen)子質(zhi)量和(he)(he)(he)(he)低(di)交聯度(du),與溶(rong)劑型雙(shuang)組(zu)分(fen)(fen)聚(ju)(ju)(ju)氨酯(zhi)涂(tu)(tu)料(liao)(liao)相(xiang)比(bi),單組(zu)分(fen)(fen)水(shui)(shui)性(xing)(xing)(xing)聚(ju)(ju)(ju)氨酯(zhi)地坪(ping)涂(tu)(tu)料(liao)(liao)的(de)(de)耐化學品性(xing)(xing)(xing)和(he)(he)(he)(he)耐溶(rong)劑性(xing)(xing)(xing)不良(liang),硬度(du)、表(biao)面光澤度(du)和(he)(he)(he)(he)鮮艷(yan)性(xing)(xing)(xing)都較(jiao)低(di),目前僅(jin)應用于建筑涂(tu)(tu)料(liao)(liao)領域(yu)及(ji)其(qi)它一些(xie)使用要求不高(gao)的(de)(de)場合。水(shui)(shui)性(xing)(xing)(xing)雙(shuang)組(zu)分(fen)(fen)聚(ju)(ju)(ju)氨酯(zhi)地坪(ping)涂(tu)(tu)料(liao)(liao)是(shi)(shi)(shi)由(you)含羥基(ji)水(shui)(shui)性(xing)(xing)(xing)多元醇組(zu)分(fen)(fen)和(he)(he)(he)(he)水(shui)(shui)性(xing)(xing)(xing)多異(yi)氰酸(suan)酯(zhi)固化劑組(zu)成,它將雙(shuang)組(zu)分(fen)(fen)聚(ju)(ju)(ju)氨酯(zhi)涂(tu)(tu)料(liao)(liao)的(de)(de)高(gao)性(xing)(xing)(xing)能和(he)(he)(he)(he)水(shui)(shui)性(xing)(xing)(xing)涂(tu)(tu)料(liao)(liao)的(de)(de)低(di)VOC相(xiang)結合,是(shi)(shi)(shi)當(dang)(dang)前地坪(ping)涂(tu)(tu)料(liao)(liao)的(de)(de)研究熱點和(he)(he)(he)(he)發展方向。
3.1羥基組分的(de)水(shui)性化
根據水(shui)性雙組分聚氨酯地坪涂料中(zhong)使用的(de)含(han)羥基組分在水(shui)中(zhong)的(de)粒子大小和(he)制備方法的(de)不(bu)同,可將其(qi)分為(wei)乳液(ye)型丙烯酸多元醇(chun)和(he)水(shui)分散體型多元醇(chun),它們各具不(bu)同的(de)特點。
3.1.1乳液型丙烯酸多元醇(chun)
乳(ru)(ru)液型多(duo)元(yuan)(yuan)醇是通(tong)過(guo)乳(ru)(ru)液聚(ju)合而(er)成的具有多(duo)種結(jie)構的丙(bing)烯酸(suan)乳(ru)(ru)液多(duo)元(yuan)(yuan)醇,其主要特(te)點為[12]:聚(ju)合物的相(xiang)對分(fen)子質量大(da),羥基(ji)當量大(da),配制(zhi)雙組(zu)分(fen)涂(tu)(tu)料所需的異(yi)(yi)(yi)氰酸(suan)酯(zhi)(zhi)固化(hua)劑少,成本低(di)。乳(ru)(ru)液對異(yi)(yi)(yi)氰酸(suan)酯(zhi)(zhi)的潤濕分(fen)散(san)性差,必須使(shi)(shi)用親(qin)水(shui)性強的水(shui)性異(yi)(yi)(yi)氰酸(suan)酯(zhi)(zhi)固化(hua)劑,即使(shi)(shi)這樣,得到高光涂(tu)(tu)膜(mo)仍很困難,而(er)且(qie)涂(tu)(tu)膜(mo)在室溫下干(gan)(gan)燥速度快,在化(hua)學交聯前已物理(li)干(gan)(gan)燥成膜(mo),因而(er)涂(tu)(tu)膜(mo)的物理(li)機(ji)械性能和耐化(hua)學品性不佳(jia)[13-14]。
3.1.2分散(san)體型多元醇
分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)型(xing)(xing)多(duo)元醇(chun)(chun)(chun)也稱第2代水(shui)(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)羥(qian)基樹脂。分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)型(xing)(xing)多(duo)元醇(chun)(chun)(chun)按化(hua)學結構可分(fen)(fen)(fen)(fen)(fen)(fen)為聚(ju)酯(zhi)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)、丙(bing)烯(xi)酸(suan)(suan)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)、聚(ju)氨(an)(an)酯(zhi)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)等(deng)。聚(ju)酯(zhi)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)是(shi)由(you)(you)過(guo)量多(duo)元醇(chun)(chun)(chun)、多(duo)元酸(suan)(suan)經酯(zhi)化(hua)反(fan)應、中和后(hou)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)在(zai)水(shui)(shui)(shui)(shui)(shui)(shui)中制(zhi)得(de)的(de)(de)[15]。聚(ju)酯(zhi)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)制(zhi)備(bei)的(de)(de)地(di)(di)(di)坪(ping)(ping)涂(tu)(tu)料具有良好(hao)的(de)(de)流(liu)動性(xing)(xing)(xing),涂(tu)(tu)膜(mo)的(de)(de)光澤較(jiao)高,但(dan)聚(ju)酯(zhi)多(duo)元醇(chun)(chun)(chun)的(de)(de)酯(zhi)鍵易水(shui)(shui)(shui)(shui)(shui)(shui)解,導致涂(tu)(tu)料的(de)(de)貯存穩定性(xing)(xing)(xing)差,這(zhe)種(zhong)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)在(zai)地(di)(di)(di)坪(ping)(ping)涂(tu)(tu)料中應用(yong)(yong)較(jiao)少。聚(ju)氨(an)(an)酯(zhi)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)的(de)(de)制(zhi)備(bei)方法與單(dan)組(zu)分(fen)(fen)(fen)(fen)(fen)(fen)水(shui)(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)聚(ju)氨(an)(an)酯(zhi)的(de)(de)制(zhi)備(bei)相(xiang)似[16-17],采(cai)用(yong)(yong)含羥(qian)基鏈(lian)終止進(jin)行擴鏈(lian),配制(zhi)的(de)(de)水(shui)(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)雙(shuang)組(zu)分(fen)(fen)(fen)(fen)(fen)(fen)聚(ju)氨(an)(an)酯(zhi)地(di)(di)(di)坪(ping)(ping)涂(tu)(tu)料具有優異(yi)(yi)的(de)(de)機(ji)械性(xing)(xing)(xing)能(neng)(neng),如柔(rou)韌性(xing)(xing)(xing)和耐(nai)磨性(xing)(xing)(xing),以及優異(yi)(yi)的(de)(de)耐(nai)化(hua)學品(pin)性(xing)(xing)(xing),但(dan)其使用(yong)(yong)成本較(jiao)高,在(zai)實際中使用(yong)(yong)較(jiao)少。丙(bing)烯(xi)酸(suan)(suan)多(duo)元醇(chun)(chun)(chun)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)是(shi)由(you)(you)含羥(qian)基丙(bing)烯(xi)酸(suan)(suan)單(dan)體(ti)(ti)和丙(bing)烯(xi)酸(suan)(suan)(酯(zhi))單(dan)體(ti)(ti)在(zai)溶(rong)劑中通過(guo)自由(you)(you)基聚(ju)合(he),中和分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)在(zai)水(shui)(shui)(shui)(shui)(shui)(shui)中制(zhi)得(de)的(de)(de),有時(shi)需(xu)要(yao)脫除部(bu)分(fen)(fen)(fen)(fen)(fen)(fen)或全部(bu)溶(rong)劑。該類分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)的(de)(de)相(xiang)對分(fen)(fen)(fen)(fen)(fen)(fen)子質(zhi)量較(jiao)低(di),羥(qian)基官能(neng)(neng)團含量較(jiao)高,與水(shui)(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)異(yi)(yi)氰(qing)酸(suan)(suan)酯(zhi)固(gu)化(hua)劑配合(he)制(zhi)成地(di)(di)(di)坪(ping)(ping)涂(tu)(tu)料后(hou),具有較(jiao)好(hao)的(de)(de)流(liu)平性(xing)(xing)(xing),干(gan)燥(zao)速度(du)慢,涂(tu)(tu)膜(mo)干(gan)燥(zao)后(hou)具有較(jiao)好(hao)的(de)(de)豐(feng)滿(man)度(du)和光澤,同時(shi)具有良好(hao)的(de)(de)物(wu)理(li)機(ji)械性(xing)(xing)(xing)能(neng)(neng)和耐(nai)化(hua)學品(pin)性(xing)(xing)(xing),基本達到溶(rong)劑型(xing)(xing)聚(ju)氨(an)(an)酯(zhi)地(di)(di)(di)坪(ping)(ping)涂(tu)(tu)料的(de)(de)性(xing)(xing)(xing)能(neng)(neng),這(zhe)種(zhong)分(fen)(fen)(fen)(fen)(fen)(fen)散(san)(san)(san)(san)(san)(san)體(ti)(ti)是(shi)目前水(shui)(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)雙(shuang)組(zu)分(fen)(fen)(fen)(fen)(fen)(fen)聚(ju)氨(an)(an)酯(zhi)地(di)(di)(di)坪(ping)(ping)涂(tu)(tu)料研(yan)究和開(kai)發的(de)(de)熱點。
3.2水性異氰酸酯(zhi)固化(hua)劑(ji)
未改(gai)(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)的(de)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)在(zai)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)雙組(zu)分(fen)(fen)(fen)(fen)聚(ju)氨(an)酯(zhi)(zhi)地(di)坪(ping)(ping)涂(tu)料中(zhong)(zhong)(zhong)的(de)應用受到限制,因(yin)為(wei)(wei)它們很難與水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)羥(qian)基(ji)(ji)(ji)組(zu)分(fen)(fen)(fen)(fen)混合均(jun)勻,兩相間容易分(fen)(fen)(fen)(fen)離。要想使異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)和水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)羥(qian)基(ji)(ji)(ji)組(zu)分(fen)(fen)(fen)(fen)均(jun)勻混合,根本途徑是將(jiang)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)化(hua)(hua)(hua)(hua)(hua)(hua)。早期使用陽離子型(xing)或非離子型(xing)外(wai)部乳(ru)化(hua)(hua)(hua)(hua)(hua)(hua)劑(ji)強制乳(ru)化(hua)(hua)(hua)(hua)(hua)(hua)使異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)分(fen)(fen)(fen)(fen)散在(zai)水(shui)(shui)(shui)(shui)(shui)中(zhong)(zhong)(zhong)[18],其(qi)乳(ru)化(hua)(hua)(hua)(hua)(hua)(hua)劑(ji)用量(liang)大(da),分(fen)(fen)(fen)(fen)散后(hou)粒子較(jiao)粗、貯存穩定性(xing)(xing)(xing)(xing)(xing)(xing)(xing)差(cha)、涂(tu)層(ceng)的(de)耐化(hua)(hua)(hua)(hua)(hua)(hua)學品性(xing)(xing)(xing)(xing)(xing)(xing)(xing)差(cha)。為(wei)(wei)了克服外(wai)乳(ru)化(hua)(hua)(hua)(hua)(hua)(hua)法的(de)缺(que)陷,近年(nian)來采用親水(shui)(shui)(shui)(shui)(shui)組(zu)分(fen)(fen)(fen)(fen)對(dui)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)進(jin)行(xing)改(gai)(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing),使其(qi)能(neng)達到自乳(ru)化(hua)(hua)(hua)(hua)(hua)(hua)的(de)目的(de)。這其(qi)中(zhong)(zhong)(zhong),以德國(guo)Bayer公司對(dui)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)化(hua)(hua)(hua)(hua)(hua)(hua)的(de)研究最為(wei)(wei)成功(gong)。到目前(qian)為(wei)(wei)止,已成功(gong)將(jiang)第(di)3代(dai)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)固化(hua)(hua)(hua)(hua)(hua)(hua)劑(ji)產品市(shi)場化(hua)(hua)(hua)(hua)(hua)(hua)[19]。第(di)1代(dai)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)通過(guo)用不足量(liang)聚(ju)醚醇(chun)對(dui)如HDI或IPDI三(san)聚(ju)體(ti)進(jin)行(xing)部分(fen)(fen)(fen)(fen)氨(an)基(ji)(ji)(ji)甲酸(suan)(suan)(suan)酯(zhi)(zhi)化(hua)(hua)(hua)(hua)(hua)(hua),這樣,親水(shui)(shui)(shui)(shui)(shui)改(gai)(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)的(de)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)(如Bayhydur 3100)易于(yu)(yu)手動(dong)乳(ru)化(hua)(hua)(hua)(hua)(hua)(hua)于(yu)(yu)水(shui)(shui)(shui)(shui)(shui)中(zhong)(zhong)(zhong),但是這種改(gai)(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)卻(que)導致(zhi)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)平均(jun)官能(neng)度(du)降(jiang)低(di),因(yin)而(er)所得(de)的(de)涂(tu)膜(mo)交聯密度(du)低(di),降(jiang)低(di)了其(qi)耐化(hua)(hua)(hua)(hua)(hua)(hua)學品性(xing)(xing)(xing)(xing)(xing)(xing)(xing)。第(di)2代(dai)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi)在(zai)第(di)1代(dai)產品的(de)基(ji)(ji)(ji)礎上,通過(guo)脲基(ji)(ji)(ji)甲酸(suan)(suan)(suan)酯(zhi)(zhi)化(hua)(hua)(hua)(hua)(hua)(hua),提高產品的(de)官能(neng)度(du),產品更疏水(shui)(shui)(shui)(shui)(shui),制備的(de)涂(tu)膜(mo)綜合性(xing)(xing)(xing)(xing)(xing)(xing)(xing)能(neng)優良,其(qi)代(dai)表產品是Bayhydur305。第(di)3代(dai)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi),采用氨(an)基(ji)(ji)(ji)磺(huang)酸(suan)(suan)(suan)鹽改(gai)(gai)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)異(yi)(yi)(yi)(yi)氰(qing)(qing)(qing)酸(suan)(suan)(suan)酯(zhi)(zhi),即(ji)使體(ti)系中(zhong)(zhong)(zhong)含(han)有(you)較(jiao)少的(de)磺(huang)酸(suan)(suan)(suan)鹽基(ji)(ji)(ji)團時(shi),也可在(zai)水(shui)(shui)(shui)(shui)(shui)中(zhong)(zhong)(zhong)很好(hao)(hao)地(di)分(fen)(fen)(fen)(fen)散,產品具有(you)較(jiao)低(di)的(de)親水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing),其(qi)代(dai)表產品有(you)BayhydurXP2547、Bayhydur XP2655,可廣(guang)泛用于(yu)(yu)環(huan)境(jing)友好(hao)(hao)型(xing)水(shui)(shui)(shui)(shui)(shui)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)雙組(zu)分(fen)(fen)(fen)(fen)聚(ju)氨(an)酯(zhi)(zhi)地(di)坪(ping)(ping)涂(tu)料中(zhong)(zhong)(zhong),涂(tu)料的(de)干燥(zao)、固化(hua)(hua)(hua)(hua)(hua)(hua)和耐化(hua)(hua)(hua)(hua)(hua)(hua)學品等性(xing)(xing)(xing)(xing)(xing)(xing)(xing)能(neng),完全可比擬溶(rong)劑(ji)型(xing)雙組(zu)分(fen)(fen)(fen)(fen)聚(ju)氨(an)酯(zhi)(zhi)地(di)坪(ping)(ping)涂(tu)料。
德國Bayer公(gong)司成功采(cai)用(yong)丙烯(xi)酸多(duo)元(yuan)醇分(fen)散體和新(xin)研制的第3代(dai)水(shui)性異氰(qing)酸酯固(gu)化劑配成水(shui)性雙組(zu)分(fen)聚氨酯地坪(ping)涂料(liao),對奧運會場(chang)館(guan)——國家游泳(yong)中心(xin)的泡(pao)泡(pao)吧地坪(ping)進行了涂裝,涂裝和使用(yong)效果(guo)受到(dao)大家的認可,整(zheng)個體系近于零VOC,其環保性更是完全貼合“綠色奧運”之理念(nian)[20]。
4結語
隨(sui)著人們對健康和環保的(de)關注,以及涂(tu)(tu)(tu)料科學(xue)技術的(de)進(jin)步(bu),地坪(ping)(ping)涂(tu)(tu)(tu)料的(de)水(shui)性(xing)(xing)化得到了(le)快速發展(zhan),在許多性(xing)(xing)能方面(mian)已接近或達到溶劑型(xing)地坪(ping)(ping)涂(tu)(tu)(tu)料的(de)水(shui)平(ping),但是(shi)水(shui)性(xing)(xing)地坪(ping)(ping)涂(tu)(tu)(tu)料作(zuo)為水(shui)性(xing)(xing)涂(tu)(tu)(tu)料還是(shi)存在明顯的(de)不足,如(ru)對施工(gong)過程及基材表(biao)(biao)(biao)(biao)面(mian)清(qing)潔度(du)要(yao)求(qiu)高,因水(shui)的(de)表(biao)(biao)(biao)(biao)面(mian)張力大,污物(wu)易使(shi)涂(tu)(tu)(tu)膜產(chan)生縮孔(kong),形成表(biao)(biao)(biao)(biao)面(mian)缺(que)陷。特(te)別對面(mian)涂(tu)(tu)(tu)而言,表(biao)(biao)(biao)(biao)面(mian)缺(que)陷是(shi)致命的(de)硬傷。水(shui)性(xing)(xing)涂(tu)(tu)(tu)料不適(shi)宜(yi)在冬季(ji)或低溫(wen)環境施工(gong),如(ru)空氣濕度(du)大,特(te)別是(shi)低溫(wen)高濕時,更不宜(yi)施工(gong);固化后(hou)交(jiao)聯(lian)密(mi)度(du)比溶劑型(xing)涂(tu)(tu)(tu)料低,涂(tu)(tu)(tu)層(ceng)(ceng)結(jie)構疏松;涂(tu)(tu)(tu)層(ceng)(ceng)的(de)表(biao)(biao)(biao)(biao)面(mian)光澤、豐滿度(du)與溶劑型(xing)地坪(ping)(ping)涂(tu)(tu)(tu)料仍有(you)一定(ding)的(de)差距。如(ru)何進(jin)一步(bu)提高水(shui)性(xing)(xing)地坪(ping)(ping)涂(tu)(tu)(tu)料的(de)綜合(he)性(xing)(xing)能,仍是(shi)我(wo)們涂(tu)(tu)(tu)料工(gong)作(zuo)者(zhe)今后(hou)努力的(de)方向。